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A novel cycloaddition reaction of 4-bromo-2,6-dimethyl-phenylisonitrile with acetylene derivatives

✍ Scribed by Takeo Takizawz; Naruyoshi Obata; Yoshio Suzuki; Tomotaka Yanagida


Book ID
104229900
Publisher
Elsevier Science
Year
1969
Tongue
French
Weight
187 KB
Volume
10
Category
Article
ISSN
0040-4039

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Formal [6+4] cycloaddition of a dicobalt
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An efficient method for constructing a 10-membered carbocycle with an oxygen bridge has been developed on the basis of a formal [6+4] cycloaddition reaction. Under the influence of EtAlCl 2 , a dicobalt hexacarbonyl acetylene complex possessing a benzoyloxy group and an allylsilane moiety reacted wi