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A Novel Cycloaddition Reaction for Obtaining Polycyclic 2,2,3,3-Tetrasubstituted-1H-indoles

✍ Scribed by Satomura, Masato; Takeda, Akihiko; Katoh, Hajime

Book ID
126854201
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
363 KB
Volume
59
Category
Article
ISSN
0022-3263

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✍ Leon W.A van Berkom; George J.T Kuster; Faysal Kalmoua; RenΓ© de Gelder; Hans W S πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 French βš– 190 KB

2-Methoxybuta-1,3-diene reacts under high pressure conditions in a one-pot domino (4+2)/(4+2)/(3+2) cycloaddition reaction with a dienophile, b-nitrostyrene and a dipolarophile to give tri, tetra and pentacyclic nitroso acetals. In this novel domino reaction up to six bonds and up to eight stereogen