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A Novel Cyclization of 4-Acetyl-1-methoxy-1-cyclohexene to 4-Alkoxybicyclo[2.2.2]octan-2-ones 1

โœ Scribed by Morita, Ken-ichi; Kobayashi, Tsuneo


Book ID
125940746
Publisher
American Chemical Society
Year
1966
Tongue
English
Weight
570 KB
Volume
31
Category
Article
ISSN
0022-3263

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(Z)-2-(4-Methoxyยญbenzylยญidene)-1-azaยญbic
โœ Sonar, Vijayakumar N. ;Parkin, Sean ;Crooks, Peter A. ๐Ÿ“‚ Article ๐Ÿ“… 2006 ๐Ÿ› International Union of Crystallography ๐ŸŒ English โš– 98 KB

The title compound, C 15 H 17 NO 2 , was prepared by the basecatalyzed reaction of 4-methoxybenzaldehyde with 1-azabicyclo[2.2.2]octan-3-one. The configuration about the olefinic bond connecting the methoxyphenyl and 1-azabicylo[2.2.2]octan-3-one moieties is Z.