## Abstract Methylmercury(II) transfer from two heterocyclic thiones to a wide variety of other ligands and the reverse reaction have been investigated by the temperature‐jump method. The reactions are almost diffusion controlled, even when the free energy difference is negligible. The only excepti
A novel correlative relationship among rates of complexation of 1:1 copper(II) diketonates and basicity of the ligand
✍ Scribed by Jesus Verdú; Carlos A. Blanco
- Publisher
- John Wiley and Sons
- Year
- 1994
- Tongue
- English
- Weight
- 253 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0538-8066
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✦ Synopsis
An exceptional kinetic behavior on the reactivity of P-diketones against copper(I1) have been found. Some relationship between ligand basicity and unexpected enhancement on the rates of complex formation, which may be useful for predicting rate constants of similar monochelated copper(I1) complexes, are established.
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