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A novel copper(II) complex with a photochromic ligand

✍ Scribed by A.N. Sunder Ram; C.P. Prabhakaran


Publisher
Elsevier Science
Year
1980
Weight
162 KB
Volume
16
Category
Article
ISSN
0020-1650

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## Abstract We report the structure, properties and a mechanism for the catecholase activity of a tetranuclear carbonato‐bridged copper(II) cluster with the macrocyclic ligand [22]pr4pz (9,22‐dipropyl‐1,4,9,14,17,22,27,28,29, 30‐decaazapentacyclo[22.2.1.1^4,7^.1^11,14^. 1^17,20^]triacontane‐5,7(28)

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Bruker SMART CCD area-detector diffractometer Absorption correction: multi-scan (SADABS; Bruker, 2000) T min = 0.667, T max = 0.747 15163 measured reflections 5500 independent reflections 4143 reflections with I > 2(I) R int = 0.032 Refinement R[F 2 > 2(F 2 )] = 0.035 wR(F 2 ) = 0.089 S = 1.01 5500