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A novel consecutive reaction of lithium acetylides with 2-aryl-1-chlorovinyl p-tolyl sulfoxides leading to the formation of (Z)-enediynes

โœ Scribed by Kimura, Tsutomu; Nishimura, Yuka; Ishida, Naoyuki; Momochi, Hitoshi; Yamashita, Hironori; Satoh, Tsuyoshi


Book ID
122776874
Publisher
Elsevier Science
Year
2013
Tongue
French
Weight
366 KB
Volume
54
Category
Article
ISSN
0040-4039

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Reaction of 1-Chlorovinyl p-Tolyl Sulfox
โœ Tsuyoshi Satoh; Hiroyuki Ota ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 170 KB

AbstractรTreatment of 1-chlorovinyl p-tolyl sulfoxides derived from ketones with cyanomethyllithium gave cyclopentadienyl enaminonitriles in high yields with three consecutive carbonยฑcarbon bond-formations. However, the 1-chlorovinyl p-tolyl sulfoxides derived from aldehydes did not give good result