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A Novel Class of Modified Nucleosides: Synthesis of Alkylidene Isoxazolidinyl Nucleosides Containing Thymine

✍ Scribed by Anna Piperno; Antonio Rescifina; Antonino Corsaro; Maria A. Chiacchio; Antonio Procopio; Roberto Romeo

Book ID
102172413
Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
114 KB
Volume
2007
Category
Article
ISSN
1434-193X

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Anomeric Ξ±and Ξ²-N,O-psiconucleosides were prepared by 1,3-dipolar cycloaddition of C-ethoxycarbonyl N-methyl nitrone with ethyl 2-acetyloxyacrylate, followed by VorbrΓΌggen nucleosidation. The synthetic scheme has been applied to all purine and pyrimidine nucleobases. Nucleosidation can proceed under