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A Novel Chiral (salen)AlIII Complex Catalyzed Asymmetric Cyanosilylation of Aldehydes

✍ Scribed by Zebing Zeng; Guofeng Zhao; Zhenghong Zhou; Chuchi Tang

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
112 KB
Volume
2008
Category
Article
ISSN
1434-193X

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## Abstract New bifunctional __N__‐oxide salen–Ti^IV^ complexes and a pyrrolidine salen–Ti^IV^ complex in combination with achiral __N__‐oxide were developed and applied to the asymmetric addition of trimethylsilyl cyanide to aldehydes. Notably, both enantiomers of trimethylsilyl ethers of cyanohyd