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A novel cell for the energy efficient electrolytic production of fluorine

โœ Scribed by AlexanderM. Saprokhin; DavidJ. Friedland; RichardM. Baran; JungT. Kim; LynnE. McCurry; RichardE. Eibeck

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
52 KB
Volume
35
Category
Article
ISSN
0022-1139

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The formation and role of carbocations in electrolytic fluorination using hydrogen fluoride electrolytes in a nafion membrane-divided teflon cell
โœ Francis Huba; Ernest B. Yeager; George A. Olah ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 495 KB

Nafion@ cation permselective membrane was used in anhydrous hydrogen fluoride (AHF) in a series of electrofluorinations of organic compounds. The carbocations generated chemically and elec- trochemically in the anode compartment, crossed the membrane under the influence of electric field, and were q