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A novel CeIII-cyclam type complex and its redox chemistry in aqueous solutions

✍ Scribed by Guy Yardeni; Israel Zilbermann; Eric Maimon; Haim Cohen; Dan Meyerstein


Book ID
106517808
Publisher
Springer Netherlands
Year
2009
Tongue
English
Weight
528 KB
Volume
35
Category
Article
ISSN
0922-6168

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Novel terpyridine macrocyclic complexing
✍ Chantal Galaup; Jean Marc Couchet; Claude Picard; Pierre TisnΓ¨s πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 French βš– 93 KB

A very convenient synthesis of an 18-membered triaza-macrocyclic ligand bearing one endocyclic terpyridine unit and three acetate pendant groups is reported. This nonadentate ligand forms very stable neutral lanthanide complexes in aqueous solution and efficiently shields the metal ion from the wate