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A novel carbon leaving group in the reaction of organometallic compounds with phosphine oxides

✍ Scribed by Cosimo Cardellicchio; Giuseppe Fracchiolla; Francesco Naso; Paolo Tortorella; Wieslawa Holody; K.Michal Pietrusiewicz

Publisher: Elsevier Science
Year: 1999
Tongue: French
Weight: 201 KB
Volume: 40
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(99)01110-7

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✦ Synopsis

The reaction of diphenyl(methoxymethyl)phosphine oxide 1 with organometallic reagents was found to lead to substitution of the methoxymethyl group. The P-phenyl substituent showed a lower propensity to undergo a displacement.

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