A Novel Borosilicate Cage Compound with an Incomplete B4Si4 Cube Structure: [(tBuSi)4(CH2=CHC6H4B)4O10]
✍ Scribed by Lorraine A. Neville; Trevor R. Spalding; George Ferguson
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 132 KB
- Volume
- 112
- Category
- Article
- ISSN
- 0044-8249
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## Abstract For Abstract see ChemInform Abstract in Full Text.
Two coordination polymers 1 ϱ {[Cd(phen)](C 6 H 8 O 4 ) 3/3 } (1) and 1 ϱ {[Cd(phen)](C 7 H 10 O 4 ) 3/3 } • 2H 2 O (2) were structurally characterized by single crystal X-ray diffraction methods. In 1 (C2/ c (no. 15), a ϭ 16.169(2) A ˚, b ϭ 15.485(2) A ˚, c ϭ 14.044(2) A ˚, β ϭ 112.701(8)°, U ϭ 324
The ab initio electronic structure calculations at the MP2 and the Becke Ž . 3LYP density functional levels in conjunction with the 6-311qqG 2 df, 2 pd basis set were used for the determination of the structure, vibrational spectra, and dissociation 2q 2q Ž . energies of the XH and XH X s C, Si, Ge