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A novel benzoyl-type fluorous protecting group for use in fluorous synthesis

โœ Scribed by Tsuyoshi Miura; Ai Satoh; Kohtaro Goto; Yasuoki Murakami; Nobuyuki Imai; Toshiyuki Inazu


Book ID
108283876
Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
118 KB
Volume
16
Category
Article
ISSN
0957-4166

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Total synthesis of cucurbitoside A using
โœ Masaru Kojima; Yutaka Nakamura; Atsushi Nakamura; Seiji Takeuchi ๐Ÿ“‚ Article ๐Ÿ“… 2009 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 234 KB

The first total synthesis of cucurbitoside A was achieved using a new fluorous N-phenylcarbamoyl ( F Car) protecting group. The F Car group was introduced into carbohydrates in high yield and was selectively removed with Bu 4 NNO 2 without damaging other acyl protecting groups. The synthetic interme