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A novel and green version of the Passerini reaction in an ionic liquid ([bmim][BF 4 ])

โœ Scribed by Fan, Xuesen; Li, Yanzhen; Zhang, Xinying; Qu, Guirong; Wang, Jianji


Book ID
123616394
Publisher
NRC Research Press
Year
2006
Tongue
French
Weight
76 KB
Volume
84
Category
Article
ISSN
0008-4042

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[Bmim]BF4 ionic liquid: a novel reaction
โœ J.S. Yadav; B.V.S. Reddy; A.K. Basak; A. Venkat Narsaiah ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 174 KB

Epoxides undergo smooth ring-opening with aryl amines in 1-butyl-3-methylimidazolium tetrafluoroborate ([bmim]BF 4 ) or 1-butyl-3-methylimidazolium hexafluorophosphate ([bmim]PF 6 ) ionic liquids under mild and neutral conditions to afford the corresponding b-amino alcohols in excellent yields with