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A novel and efficient synthesis of the aspidosperma alkaloid ring system: N(a)-benzyldeethylaspidospermidine

โœ Scribed by Gramain, Jean-Claude; Husson, Henri Philippe; Troin, Yves

Book ID
117999942
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
550 KB
Volume
50
Category
Article
ISSN
0022-3263

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A new strategy for the enantioselective
A new strategy for the enantioselective synthesis of aspidosperma alkaloids: II - Achievement of the pentacyclic system.
โœ Didier Desmaele; Jean d'Angelo ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 271 KB

## Carbazolone 5 has been converted in eleven steps into alkaloid analog Z (R = Me) (13 46 overall yield). In the preceding paper l, we proposed a new approach to pentacyclic Aspidosperma alkaloids [(e.g. (-)-aspidospermldine, 1, R = Et], based on the disconnection [l -+ 2 -+ 31, in which carbazol