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A Novel and Convenient Protocol for Synthesis of α-Haloacrylates

✍ Scribed by Jiang, Biao; Dou, Ying; Xu, Xiangya; Xu, Min

Book ID
127350283
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
74 KB
Volume
10
Category
Article
ISSN
1523-7060

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📜 SIMILAR VOLUMES

A convenient method for the synthesis of
A convenient method for the synthesis of (Z)-α-haloacrylates: Lewis base-catalyzed carbonyl olefination using α-halo-C,O-bis(trimethylsilyl)ketene acetals
✍ Makoto Michida; Takako Toriumi; Teruaki Mukaiyama 📂 Article 📅 2009 🏛 Elsevier Science 🌐 French ⚖ 221 KB

A highly useful method for the stereoselective synthesis of (Z)-a-haloacrylates from various aldehydes that uses a-halogenated ethyl-C,O-bis(trimethylsilyl)ketene acetals in the presence of a Lewis base catalyst such as acetate salts was established. This procedure gives the corresponding a-halo-a,b