A novel anagostic CH⋯Cu interaction and clustered water molecules in copper(II)–pyridine-2,5-dicarboxylate complex
✍ Scribed by Alper Tolga Çolak; Okan Zafer Yeşilel; Orhan Büyükgüngör
- Book ID
- 103839810
- Publisher
- Elsevier Science
- Year
- 2011
- Tongue
- English
- Weight
- 686 KB
- Volume
- 991
- Category
- Article
- ISSN
- 0022-2860
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Blue crystals of Cu 2 (phen) 2 (H 2 O) 2 (C 5 H 6 O 4 ) 2 were obtained from a CH 3 OH±H 2 O solution containing CuCl 2 , 1,10-phenanthroline (phen), glutaric acid and Na 2 CO 3 . The crystal structure (monoclinic, P2 1 /c (no. 14), a = 10.271(1), b = 10.595(1), c = 15.585(1) A Ê , b = 107.105(3)°,
Three copper(II) complexes of type [Cu(pyca)(Cl)(Y)] (1-3) [pyca = bis(pyridin-2-carbonyl)amine; Y = NCO À , N 3 À , NCS À ] have been synthesized and characterized on the basis of microanalytical, spectroscopic, magnetic, electrochemical, and other physicochemical properties. X-ray diffraction stud