Dinitrobenzoic acid, 1, forms a 2:1 molecular complex with 1,4-diiodobenzene, 2, through the formation of iodo-nitro interactions utilising one of its nitro groups, rather than forming a 1 : 1 molecular complex using both the nitro groups. The result suggests the importance of the hydrogen bond inte
✦ LIBER ✦
A novel additive organic supramolecular assembly: molecular complex of 3,5-dinitrobenzamide and 3,5-dinitrobenzonitrile
✍ Scribed by V.R Pedireddi; J PrakashaReddy; Kapildev K Arora
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- French
- Weight
- 319 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
Co-crystallization of 3,5-dinitrobenzamide and 3,5-dinitrobenzonitrile forms an additive assembly, in which simple addition of the hydrogen bonded networks that exist in the native crystal structures of the constituent compounds takes place. The additive nature is reflected in the unit cell dimensions of the assembly, with the c-axis in the assembly being nearly the same as the sum of the c-axes observed in the crystal structures of the constituents.
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