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A novel 3(2H)-furanone-2(5H)-furanone rearrangement

โœ Scribed by Mack, Robert A.; St. Georgiev, Vassil


Book ID
127079947
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
220 KB
Volume
52
Category
Article
ISSN
0022-3263

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A novel rearrangement of 2(5H)-furanones
โœ Robert A. Mack; Thomas R. DeCory; Vassil St. Georgiev ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 281 KB

A novel rearrangement of 2(SH)-furanones is described. When refluxed in aq. ethanolic solution in the presence of excess KOH, the 2,5-dihydro-2-oxofuran-3-carboxamides 6 underwent a novel rearrangement to the corresponding 4,5-dihydro-4-oxo-2-(phenylamino)-3-furancarboxylic acids 1 in moderate-to-ex