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A novel 1D polyoxometallate-based coordination polymer [{Pr(DMSO)6(H2O)}(PMo12O40)·CH3CN]n: properties, crystal structure and characterization

✍ Scribed by Jing-Yang Niu; Mei-Lin Wei; Jing-Ping Wang

Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
217 KB
Volume
689
Category
Article
ISSN
0022-2860

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## Abstract The structures of three 1:1 composite compounds prepared with the polyoxometalate (POM) [PMo~12~O~40~]^3−^ and the cations [Ln(NMP)~6~]^3+^ [Ln = La (1), Ce (3), Pr (2); NMP = __N__‐methyl‐2‐pyrrolidone] exhibit two types of zig‐zag chains with alternating cations and anions through Mo−