✦ LIBER ✦
A novel 1,3-diene- to σ,π-allyliron tricarbonyl dyotropic arrangement. Cycloaddition reactions of cycloheptatrieneiron tricarbonyl and diphenylketene.
✍ Scribed by Zeev Goldschmidt; S. Antebi
- Book ID
- 104236950
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- French
- Weight
- 190 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
The reactivity of cyclic trieneiron tricarbonyl canplexes lhas become a subject of paramount interest.l The donor character of the complexed butadiene moiety' attached to the free double bond, together with the apparent stability of the cyclic pentadienyliron tricarbonyl cation 2 3 makes this system extremely useful in reactions with electrophiles. 1 Uniparticulate electrophiles (EN) , e.g., tetracyanoethylene (TCNE), N-phenyl-tri-