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A nonresolutive approach to the preparation of configurationally pure difunctional molecules

✍ Scribed by Chillous, Sandra; Hart, David J.; Hutchinson, Douglas K.

Book ID
127077485
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
415 KB
Volume
47
Category
Article
ISSN
0022-3263

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A new approach to the selective alkylati
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Alkylation of some diamines containing both tertiary and primary amino groups is described; it proceeds exclusively with less nucleophilic tertiary amino group when an appropriate lanthanide chelate is added to the reaction mixture. Under similar conditions the alkylation of 3-(tetrahydro-2-thienyl)