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A nonempirical calculation of the potential surface of the reaction CH3NH2+T→NH2T+CH3

✍ Scribed by R. S. Asatryan

Publisher
SP MAIK Nauka/Interperiodica
Year
1983
Tongue
English
Weight
240 KB
Volume
23
Category
Article
ISSN
0022-4766

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Unimolecular reactions of the isolated i
Unimolecular reactions of the isolated immonium ions CH3CH = NH+C4H9, CH3CH2Ch = NH+C4H9 and (CH3)2C = NH+C4H9
✍ Richard D. Bowen; Alex. W. Colburn; Peter J. Derrick 📂 Article 📅 1990 🏛 John Wiley and Sons 🌐 English ⚖ 858 KB

The reactions of ten metastable immonium ions of general structure R'R2C=NH+C4H9 (R' = H, R2 = CH, , C2H, ; R' = R2 = CH,) are reported and discussed. Elimination of C4H, is usually the dominant fragmentation pathway. This process gives rise to a Gaussian metastable peak; it is interpreted in terms