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A Nonanuclear Copper(II) Polyoxometalate Assembled Around a μ-1,1,1,3,3,3-Azido Ligand and Its Parent Tetranuclear Complex

✍ Scribed by Pierre Mialane; Anne Dolbecq; Jérôme Marrot; Eric Rivière; Francis Sécheresse

Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
202 KB
Volume
11
Category
Article
ISSN
0947-6539

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The crystal structure of a copper(II) complex of 2acetylpyridine 3-piperidylthiosemicarbazone, [Cu(Acpip) 2 ], indicates a tridentate, monoanionic ligand (i. e., pyridine nitrogen, imine nitrogen and thiolato sulfur atoms) and a bidentate, monanionic ligand (i. e., imine nitrogen and thiolato sulfur