A non-linear viscoelastic model for predicting the yield stress of amorphous polymers
β Scribed by G. Spathis; C. Maggana
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- English
- Weight
- 537 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0032-3861
No coin nor oath required. For personal study only.
β¦ Synopsis
A non-linear viscoelastic model is introduced by employing a new formulation where the relaxation time of rate processes is directly dependent on the induced deformation state applied to the material. The plastic flow of amorphous polymers is considered as a continuous structural change, and the yield phenomenon is modelled through the corresponding viscoelastic constitutive equations. All material constants necessary to predict the yield stress, the rate and temperature dependence are non-adjustable parameters depending on the particular deformation mode. To verify the results of the proposed model, two independent series of experiments have been performed on specific polymeric materials, and have been proved to satisfy adequately the proposed analysis.
π SIMILAR VOLUMES
## Abstract Theoretical predictions from a nonβlinear model based on the free volume concept, which were previously tested only with a molten polymer, are presented and compared with literature data of solid polyethylene. The agreement is good both when a steady state is reached in the experimental