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A Nitroxide Derivative as a Probe for Conformational Studies of Short Linear Peptides in Solution. Spectroscopic and Molecular Mechanics Investigation

โœ Scribed by Pispisa, Basilio; Palleschi, Antonio; Stella, Lorenzo; Venanzi, Mariano; Toniolo, Claudio


Book ID
120418049
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
141 KB
Volume
102
Category
Article
ISSN
0022-3654

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A spectroscopic and molecular mechanics
โœ Basilio Pispisa; Lorenzo Stella; Mariano Venanzi; Antonio Palleschi; Fernando Ma ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› Wiley (John Wiley & Sons) ๐ŸŒ English โš– 188 KB ๐Ÿ‘ 1 views

Linear Aib-based hexapeptides, of the general formula Ac-Toac-(Aib) n -Trp-(Aib) r -OtBu [T(Aib) n Trp], where n ฯฉ r ฯญ 4, and Toac is a nitroxide spin-labeled C โฃ,โฃ -disubstituted glycine, were investigated by steady-state and time-resolved fluorescence measurements in different solvent media. A rel