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A new window on fullerene chemistry: An electrospray mass spectrometric study of the amination of C60

✍ Scribed by Stephen R. Wilson; Yunhui Wu

Publisher
John Wiley and Sons
Year
1994
Tongue
English
Weight
462 KB
Volume
29
Category
Article
ISSN
1076-5174

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✦ Synopsis

Polyamines derived from C,, were characterized by electrospray ionization mass spectrometry in 1 : 1 methanoltoluene containing 2.5% trifluoroacetic acid. Peak assignments are consistent with the formula C600,(RNH2), for the protonated products. The preferential formation of the hexaaminated product C,,O,(RNH,), was also observed.

Mass spectrometry

All electrospray mass spectra were obtained on a Vestec Model 201 ESI mass spectrometer (a single quadrupole instrument'). The sample solution was infused directly CCC 0030-493X/94/040186-06 c) 1994 by John Wiley & Sons, Ltd

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