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A new way of synthesis and characterization of superconducting oxyfluoride Sr2Cu(O, F)4 + δ

✍ Scribed by E.I. Ar-nikova; S.V. Lubarsky; D.I. Denisenko; R.V. Shpanchenko; E.V. Antipov; G. Van Tendeloo

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
785 KB
Volume
253
Category
Article
ISSN
0921-4534

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La 8؊x Sr x Cu 8 O 20؊ (x ‫؍‬ 1.3, 1.5, and 1.9) compounds were 6uorinated using XeF 2 as a 6uorinating agent. The formation of a new tetragonal complex oxy6uoride La 0.813 Sr 0.187 Cu(O, F) 3؊ was observed. The structure of the new phase was re5ned using X-ray powder data (a ‫؍‬ 3.7921(3) A s , c ‫