## 3-Amino-3-cyano-3-deoxy sugars obtained by cyclization of dialdehydes with cyanoacetamide and Hojkann rearrangement were reductively decyanuted using sodium borohydn'de providing a new approach to 3-amino-3-deoq sugars. 3-Amino-3-deoxy sugars are components of aminocyclitol', macrolide', and an
A New Way for the Synthesis of 3-Amino Sugars
β Scribed by Hans Helmut Baer and Hermann O. L. Fischer
- Book ID
- 123671305
- Publisher
- National Academy of Sciences
- Year
- 1958
- Tongue
- English
- Weight
- 146 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0027-8424
- DOI
- 10.2307/89943
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## Abstract The synthesis of two new furyl amino acids as rigid isosteres of the dipeptides (D)βHβSerβ(D,L)βThrβOH and (L)βHβSerβ(D,L)βThrβOH is presented. The developed synthetic methodology starts from Dβxylose and Dβarabinose and makes use of trihydroxypropylfurans as intermediates. The key step