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A New Type of Reaction in the Benzylcyclopropane Series: The Intramolecular Cyclopropylation of an Aromatic Nucleus in the Reaction of 4-Methoxybenzylcyclopropane with Dinitrogen Tetroxide

✍ Scribed by Mochalov, S. S.; Fedotov, A. N.; Borisenko, A. A.; Tkachev, V. V.; Shilov, G. V.; Utenyshev, A. N.; Aldoshin, S. M.; Zefirov, N. S.


Book ID
111550200
Publisher
Springer
Year
2003
Tongue
English
Weight
42 KB
Volume
391
Category
Article
ISSN
0012-5008

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## Abstract Reactions of electron‐poor α‐haloketones with (__N__‐isocyanimino) triphenylphosphorane in the presence of aromatic carboxylic acids proceed smoothly at room temperature and in neutral conditions to afford disubstituted 1,3,4‐oxadiazole derivatives in high yields. Β© 2010 Wiley Periodica