Symmary: Protection of the guanine residue with the 06-diphenylcarbamoyl and N -propionyl groups is described. These protecting groups could be readily introduced and removed simultaneously. They were used to demonstrate the synthesis of the deoxyguanylate dimer in high yield.
A new type of protection mode for the Guanine residue by using 1,2-diisobutyryloxyethylene group
β Scribed by Mitsuo Sekine; Jun-ichi Matsuzaki; Tsujiaki Hata
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- French
- Weight
- 288 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
The benzylation of aliphatic alcohols with various benzylic alcohols has been achieved in the presence of BiBr 3 under mild conditions. 2-Phenylpropan-2-ol proved to be the most efficient and can be considered as a novel protecting group.
## Abstract The new protecting groups **1a**,**b** and **2a**,**b** were developed for the 5β²βOH group of deoxynucleosides by utilizing the unique characters of the sulfenate and sulfenamide linkage. These new protecting groups have a 2β(hydroxymethyl)benzoyl or 2β[(methylamino)methyl]benzoyl skele
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