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A New Ternary Arsenide LaNi5As3: Preparation and Crystal Structure.

✍ Scribed by Volodymyr Babizhetskyy; Roland Guerin; Arndt Simon


Publisher
John Wiley and Sons
Year
2005
Weight
60 KB
Volume
36
Category
Article
ISSN
0931-7597

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All six new arsenides were prepared by arc-melting of preheated mixtures of the monoarsenides MAs with the 3d metals Fe, Co, and Ni, respectively. The isostructural title compounds all form the Co 2 Si structure type, in contrast to the corresponding phosphides with ZrNiP occurring in the Ni 2 In ty