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A new synthetic route to juvenile hormone kinetic resolution of epoxides using organoaluminum reagent

✍ Scribed by Yuji Naruse; Esaki Toru; Yamamoto Hisashi


Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
203 KB
Volume
29
Category
Article
ISSN
0040-4039

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Mixed Superbase LICKOR as a Key Reagent
✍ Paolo Balma Tivola; Annamaria Deagostino; Claudia Fenoglio; Mariella Mella; Cris πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 148 KB πŸ‘ 2 views

Treatment of the dimethyl acetals of citral (1) and farnesal be subjected to a Diels-Alder reaction, which allows further synthetic elaboration. In particular, in the case of farnesal (2) with the superbase "LICKOR" in THF at low temperatures induces regioselective metallation at the allylic methyl