✦ LIBER ✦
A new synthesis ofortho-Quinones by transition-metal-mediated oxygenation of phenols withtert-butylhydroperoxide and the mimoun oxodiperoxo molybdenum complex [Mo(O2)2O] · Py · HMPT
✍ Scribed by Krohn, Karsten ;Rieger, Hagen ;Khanbabaee, Karamali
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1989
- Tongue
- English
- Weight
- 835 KB
- Volume
- 122
- Category
- Article
- ISSN
- 0009-2940
No coin nor oath required. For personal study only.
✦ Synopsis
A specific oxygenation of phenols to ortho-quinones can be effected by a combination of the transition metal complexes Ti(OiPr)4, Vqacack, Zr(acac),, Zr(0nPrh and tert-butylhydro-B 2323 Eine nene ortbChinon-Synthese dmcb Oxygenhmg vott Wen o h mit den systemen tert-Butyihydroperoxid/ObergnngsmetaU-Komplex und dem Mimowcben Oxodiperoxo-Molybornplex Fr0(02)ZOl* Py * HMpT Phenole konnen mit einer Kombination der &xgangsmetall-Komplexe Ti(OiPrk, VO(acack, Zr(acac)h Zr(0nPrk und tert-Butylhydmperoxid oder mit [Mo(O&O] . Py + HMPT spezifisch