A new synthesis of unsymmetrically substituted halophosphines
✍ Scribed by Jan Omelańczuk
- Publisher
- John Wiley and Sons
- Year
- 1992
- Tongue
- English
- Weight
- 261 KB
- Volume
- 3
- Category
- Article
- ISSN
- 1042-7163
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
Chiral, racemic alkylaryl‐, or diarylhalophosphines have been obtained in 50–70% yields by treatment of alkylaryl‐ or diaryl‐methylthiohalophosphonium triflates with triphenylphosphine in methylene chloride solution at room temperature or under reflux.
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A series of new unsymmetrically substituted subphthalocyanines containing iodo or octylthioether substituents on the outer aromatic rings have been synthesized. The statistical reaction of one equivalent of 1,2-dicyano-3-iodobenzene whether with two equivalents of 1,2-dicyano-4-octylthiobenzene or w
## Abstract For Abstract see ChemInform Abstract in Full Text.