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A New Synthesis of Methyl 3,4,6-Trimethyl-β-d-glucoside and the Preparation of Crystalline 3,4,6-Trimethyl-d-glucose

✍ Scribed by Sundberg, Robert L.; McCloskey, Chester M.; Rees, Donald E.; Coleman, George H.


Book ID
126330682
Publisher
American Chemical Society
Year
1945
Tongue
English
Weight
618 KB
Volume
67
Category
Article
ISSN
0002-7863

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Efficient and stereoselective synthesis
✍ Abdul Rashid; William Mackie 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 652 KB

Methyl 3-O-(3,6-anhydro-beta-D-galactopyranosyl)-alpha-D-galactopyranoside (3) and methyl 3,6-anhydro-4-O-beta-D-galactopyranosyl-alpha-D-galactopyranoside (4) have been synthesised stereoselectively using three coupling procedures. Acceptable yields were achieved using acetylated derivatives as don