✦ LIBER ✦

A new synthesis of epidithiapiperazinediones

✍ Scribed by T. Fukuyama; S. Nakatsuka; Y. Kishi

Book ID: 104225704
Publisher: Elsevier Science
Year: 1976
Tongue: French
Weight: 246 KB
Volume: 17
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)93053-3

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✦ Synopsis

The epidithiapiperazinedione ring is the functional group common to natural products in the gliotoxin-sporidesmin class. We reported a general synthetic method to construct the epidithiapiperazinedione system1 and demonstrated its applicability in a total synthesis of dehydrogliotoxin, 2 sporidesmin A, 3 sporidesmin B, 4 and gliotoxin.

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