A mild and convenient method for ring expansion of 1,3-dithiolans and 1,3-dithians to dihydro-1,4-dithiins and dihydro-1,4-dithiepins, respectively, using phenyl selenenyl chloride in methylene chloride is described. A mechanism involving sulphenyl chloride derivatives as intermediates is proposed.
β¦ LIBER β¦
A new synthesis of dihydro-1,4-dithiins
β Scribed by C.H. Chen
- Book ID
- 104212903
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- French
- Weight
- 199 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
β¦ Synopsis
Surveying the literature, one finds that very few examples of monosulfoxides of 1,3_ditbiolanes are known and that their chemistry is little explored.
π SIMILAR VOLUMES
Ring expansion reactions of 1,3-dithiola
β
Cosme G. Francisco; Raimundo Freire; Rosendo HernΓ‘ndez; JosΓ© A. Salazar; Ernesto
π
Article
π
1984
π
Elsevier Science
π
French
β 209 KB
Dihydro-1,4-dithiin annelation
β
Chen, C. H.; Donatelli, B. A.
π
Article
π
1976
π
American Chemical Society
π
English
β 267 KB
Preparation of substituted -5,6-dihydro-
β
Rubinstein, Harry; Wuerthele, Michael
π
Article
π
1969
π
American Chemical Society
π
English
β 294 KB
Ab initio molecular orbital study of ene
β
Freeman, Fillmore; Lee, Choonsun; Po, Henry N.; Hehre, Warren J.
π
Article
π
1998
π
John Wiley and Sons
π
English
β 228 KB
π 2 views
Optimized geometries and energies for 3,4-dihydro-1,2-dithiin Ε½ . Ε½ . Ε½ . Ε½ . 1 , 3,6-dihydro-1,2-dithiin 2 , 4H-1,3-dithiin 3 , and 2,3-dihydro-1,4-dithiin 4 were calculated using ab initio 6-31G U and MP2r6-31G U rr6-31G U methods. At the MP2r6-31G U rr6-31G U level, the half-chair conformer of 4
Synthesis of dihydro-p-dithiins and dihy
β
Massingill, John L.; Reinecke, Manfred G.; Hodgkins, Joe E.
π
Article
π
1970
π
American Chemical Society
π
English
β 430 KB
Synthesis of 1,4-Dithiins from Pentathie
β
Amelichev, Stanislav A.; Konstantinova, Lidia S.; Obruchnikova, Natalia V.; Raki
π
Article
π
2006
π
American Chemical Society
π
English
β 81 KB