A new synthesis of d1-coriolin A. Application of a new SN2 reaction at a neopentylic position

✍ Scribed by Toshio Ito; Nobuya Tomiyoshi; Koki Nakamura; Shizuo Azuma; Makoto Izawa; Fumio Maruyama; Mitsutoshi Yanagiya; Haruhisa Shirahama; Takeshi Matsumoto

• Book ID: 104220698
• Publisher: Elsevier Science
• Year: 1982
• Tongue: French
• Weight: 237 KB
• Volume: 23
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)87199-3

✦ Synopsis

Dicyclopentadiene has been stereoselectively converted to a key tricyclic intermediate for the total synthesis of coriolin, through a route which involves a new SN2 reaction at a neopentylic position.