A New Synthesis of Benzylidene Acetals
β Scribed by Chunbao Li; Andrea Vasella
- Publisher
- John Wiley and Sons
- Year
- 1993
- Tongue
- German
- Weight
- 793 KB
- Volume
- 76
- Category
- Article
- ISSN
- 0018-019X
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β¦ Synopsis
For an oxidative 4-methoxybenzylidenation, see e.g. [3a], and for a reductive benzylidenation [3b] ') A large number of fused benzylidene acetals of 1,3-diols are known, but only a few bridged ones, namely derivatives of rihopyranosides and of 8-ribonolactone [lo], of glucopyranosides [I I], and of azadirachtin [12].
π SIMILAR VOLUMES
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Pyruvic acid acetals (l-carboxyethylidene acetals) linked to aldohexopyranosyl residues are known to occur in a number of polysaccharides. These include agarl, and exocellular2 and capsular polysaccharides'. Pyruvic acid is most often linked to O-4 and O-6 of such hexoses as o-glucose, D-mannose, D-