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A new synthesis of acetato porphyrinato indium(III) from indium(III) oxide and X-ray crystal structures of In(tpyp)(OAc) and In(tmpp)(OAc)

✍ Scribed by Tay-Ning Hong; Yeong-Horng Sheu; Keh-Wen Jang; Jyh-Horung Chen; Shin-Shin Wang; Ju-Chun Wang; Sue-Lein Wang


Book ID
103654138
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
495 KB
Volume
15
Category
Article
ISSN
0277-5387

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Two New Carbon-Free Indium(III) Asymmetr
✍ Raymundo Cea-Olivares; RubΓ©n A. Toscano; SimΓ³n HernΓ‘ndez-Ortega; Josef Novosad; πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 253 KB πŸ‘ 2 views

The ligands [Ph 2 (S)PNHP(X)Ph 2 ] -(X = O, Se) react with InCl 3 coordination geometry in 2 resembles that observed in the three analogous tris-chelates incorporating the corres-in a 3:1 ratio to give a tris-chelate [In{Ph 2 P(O)NP(S)Ph 2 -O,S} 3 ]β€’0.75 C 6 H 6 (2) and the unexpected pentacoordinat