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A new synthesis of 3-aryl-4-hydroxycoumarins

โœ Scribed by B. van Zanten; U. A. Th. Brinkman; W. Th. Nauta


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
156 KB
Volume
79
Category
Article
ISSN
0165-0513

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โœฆ Synopsis


Abstract

In the course of an investigation into the synthesis and properties of 3โ€arylโ€4โ€hydroxycoumarins a new direct synthesis of these compounds was found. In an acid medium 4โ€hydroxycoumarin can be coupled directly to a diazotized aniline to form the desired 4โ€hydroxycoumarin derivative.


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## Abstract Photoinduced direct arylation of 4โ€hydroxycoumarin with halides results in formation of title compounds (III).