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A new strategy for asymmetric synthesis of aminophosphonic acid derivatives: the first enantioselective catalytic reduction of C-phosphorylated imines

✍ Scribed by Yuliya V. Rassukana; Petro P. Onys’ko; Mykola V. Kolotylo; Anatolii D. Sinitsa; Piotr Łyżwa; Marian Mikołajczyk

Publisher: Elsevier Science
Year: 2009
Tongue: French
Weight: 151 KB
Volume: 50
Category: Article
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2008.10.152

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✦ Synopsis

The first highly enantioselective catalytic reduction of 1-imino-2,2,2-trifluoroethylphosphonates and the synthesis of enantiomerically enriched biorelevant phosphonotrifluoroalanine is reported.

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