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A new strategy for 2-substituted indolylalkylamines: synthesis of 2-aryldihomotryptamines

✍ Scribed by Valentine G Nenajdenko; Eugene P Zakurdaev; Elizabeth S Balenkova

Book ID: 104252300
Publisher: Elsevier Science
Year: 2002
Tongue: French
Weight: 73 KB
Volume: 43
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(02)02105-6

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✦ Synopsis

Substituted homologues of tryptamines were synthesized in one step in high yields under mild conditions. The key intermediates are arylhydrazones of 6-aminohexanones, which undergo Fischer rearrangement readily in glacial acetic acid. An easy and ready for scale-up procedure is developed and formerly unknown 2-substituted dihomotryptamines are obtained.

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