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A New Stereoselective Synthesis of (±)-Grandisol Based on the Remote Alkylation Protocol

✍ Scribed by Hugo J. Monteiro; Helio A. Stefani

Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
257 KB
Volume
2001
Category
Article
ISSN
1434-193X

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The major product from the alkylation of thexyldialkylalkynylborates is the vinylborane in which the groups derived from the alkylating agent and from migration from boron to carbon are cis to each other. -We have recently defined conditions for the alkylation of trialkylalkynylborates (VI) leading