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A New Spin Probe of Protein Dynamics: Nitrogen Relaxation in 15 N− 2 H Amide Groups

✍ Scribed by Xu, Jun; Millet, Oscar; Kay, Lewis E.; Skrynnikov, Nikolai R.


Book ID
125995167
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
186 KB
Volume
127
Category
Article
ISSN
0002-7863

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The 2H spin-lattice relaxation times T1Z and T1Q of the -ND+3 group in polycrystalline L-alanine were measured over the temperature ranges 250-425 K and 300-425, respectively. The relaxation data were fitted to analytical expressions for three-fold reorientation, giving a correlation time tau(c) = 1