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A New Spherical Metallacryptate Compound [Na{Cu6(Thr)8(H2O)2(ClO4)4}]·ClO4·5 H2O: Magnetic Properties and DFT Calculations

✍ Scribed by Sheng-Chang Xiang; Sheng-Min Hu; Jian-Jun Zhang; Xin-Tao Wu; Jun-Qian Li

Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
150 KB
Volume
2005
Category
Article
ISSN
1434-1948

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## Abstract Four new dinuclear Mn^III^ complexes with the general formula [{Mn(bpy)L}(μ‐RCOO)~2~(μ‐O){Mn(bpy)L′}]^__n+__^ (bpy =2,2′‐bipyridine) have been synthesized with RCOO = 2‐MeC~6~H~4~COO (1, 2) and 2‐FC~6~H~4~COO (3, 4); the counteranion could be NO~3~^–^ (1, 3) or ClO~4~^–^ (2, 4), and a m