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A new skeletal rearrangement of cyclic β-haloalkylisothioureas

✍ Scribed by A. N. Pushin; S. E. Tkachenko; V. M. Fedoseev

Book ID
112444553
Publisher
Springer
Year
1986
Tongue
English
Weight
66 KB
Volume
35
Category
Article
ISSN
1573-9171

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✍ Masahiro Tada; Yoshiaki Tanahashi; Yoshihiko Moriyama; Takeyoshi Takahashi 📂 Article 📅 1972 🏛 Elsevier Science 🌐 French ⚖ 189 KB

During the course of the structural investigation of furanoeremophilane-6B, lOS-diol (1, R = H),l) we have found that ;1 (R = H) is readily transformed into farfugin A (2)2), farfugin B (z)2) and another benzofuran (4) on dehydration with POc13. We wish to report here the mechanism of these skeleta