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A new series of chiral catalysts for the enantioselective borane reduction of ketones

✍ Scribed by Zong-Xuan Shen; Ya-Wen Zhang; Jun Lu; Xue-Nong Xu; Cheng-Rong Lu

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
282 KB
Volume
15
Category
Article
ISSN
0256-7660

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✦ Synopsis

A new serica of 1,3,2-ox&rolidine catalysts sukituted in pmition 4 by the (CHa)sC(CHa), group (n=2,3,4, 5) were ryntheuized and applied to the borane reduction of prochired ketones. The relationship between catalyst structure and enantioselectivity wan d i s c d .

Keywordr,

Oxazaborolidine, enantioselective borane reduction, enmtioeelectivity.

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