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A new semiempirical equation of state for fluids—II: Application to pure substances

✍ Scribed by Ulrich Deiters

Book ID
107728861
Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
371 KB
Volume
36
Category
Article
ISSN
0009-2509

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A new semiempirical equation of state fo
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✍ Ulrich Deiters 📂 Article 📅 1981 🏛 Elsevier Science 🌐 English ⚖ 675 KB

## Abhwt -A semiempirical equation of state has been developed for non-polar and weakly polar fluid substances from the square well model of the inter-molecular pair potential. The equation of state has three adjustable parameters and contains corrections for non-spherical molecular shape, "soft"

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The equation of state derived in a previous publication[ll is used to correlate vapour-liquid, liquidliquid, and gas-gas equilibria in biiy mixtures. Special mixiig rules for the parameters of the equation of state are derived from a quasichemical lattice model. It is possible to describe phase equi